NEEP602 Course Notes (Fall 1996)
Resources from Space

Lecture #13: It's only a gassy Moon!

Title: Resources of the Moon: Solar Wind/Cosmic Ray Derived


Slides from Apollo 17


Polar H2O as ice: Clementine photos "put a human face" on the long held knowledge that there are permanently shadowed areas above and below about 70o latitude on the Moon, documenting that the floor of a large basin at the south pole is currently permanently shadowed. Other sensors gave data consistent with, but not proof of, the presence of water ice in this shadowed area.

Clementine photo of lunar south pole

o Theory indicates that if water and a few other volatiles were released some would precipitate in permanently shadowed areas (Watson, 1961, and Arnold, 1979).
o Permanently shadowed areas exist near the poles.
o Clementine photographic and radar observations of the South Pole are consistent with the presence of water ice (SPACE NEWS, 10/16-22/95).

o Apollo sample measurements show no definitive evidence of indigenous or solar proton-induced water, although theory would predict that some small quantity of solar proton-induce water should form continuously. The work of Epstein and Taylor (1973) on Deuterium and 18O relationships indicates that no water in lunar samples other than terrestrial water contamination and solar wind hydrogen reaction with the soils.
o Steady state flux of impacts would release and cause some or all water precipitated in permanently shadowed areas to be ionized and thermally accelerated to escape velocities.
o Sputtering of ice by charged particles, within the isotropic particle environment of the tail of the Earth's magnetosphere, may cause water loss unless mixing of ice and regolith is rapid enough to offer protection (Arnold, 1979).

Solar Wind Volatiles from the regolith

What are the Solar Wind Volatiles?
Hydrogen (96%)
Helium (4%)
Noble Gases (Kr, Xe, Ar)

The solar wind is the product of fusion reactions in the sun.
Origin of the Solar Wind

The structure of the solar wind in the vicinity of the Earth and Moon is profoundly affected by the Earth's magnetic field.
Figure: Structure of the Solar Wind in the vicinity of the Earth and Moon (to be supplied)

Hydrogen and helium are the principal components of the solar wind.
Composition of the Solar Wind

Because of the Moon's roughly spherical shape and its monthly passage through the magnetic tail of the Earth, the net flux of solar wind particles on the lunar surface varies significant with latitude and longitude.
Nearside: Relative flux varies from less than 10% near the poles, to about 30% at 0 Lat and 0 Long, to over 80% near the 90W and 90E.
Farside: over 90% between 30N and 30S, dropping off to less than 10% near the poles.

Based on the measured concentrations in lunar samples and extrapolations across the Moon's surface, a rough inventory of lunar volatiles in the upper 3m of the lunar surface can be made.
Inventory of Lunar Volatiles in first three meters of regolith (note log scale).
Inventory of Lunar Volatiles relative to the production of one tonne of helium-3

More specific data on helium relationships:

Measured Helium content in lunar samples by mission

A strong correlation exists between helium content and TiO2 (ilmenite) content. A much weaker correlation is that between helium and regolith maturity as measured by the increased reduction of iron in the regolith to iron metal over time.

Correlation of Helium content with TiO2 and maturity (Taylor, 1973)

The correlation of helium-3 with the product of TiO2 content and maturity, however, is very strong, at least for the samples returned so far. (Taylor, 1993)

Correlation of Helium content with (TiO2)(maturity) (Taylor, 1973)

Remote sensing from Earth and from the Clementine orbits can be used to give an approximate distribution of titanium in lunar surface materials and thus a rough indication of helium distribution, although the maturity of the soils would need to be over-laid on this distribution to give a better approximation.

Figure: Distribution of TiO2 on the lunar nearside (Johnson, 1991) (to be supplied)

The maria whose regoliths are of greatest current interest as a source of solar wind volatiles, such as 3He for fusion power, are those that are oldest and most titanium-rich. Such maria appear to be most abundant in the vicinity of Tranquillitatis. In fact, there are indications that mare eruptions over time may have been roughly concentric to this region and contained less and less titanium on the average.
Titanium content of soils in Mare Tranquillitatis (after Cameron, 1992).
Estimated helium resource base in Mare Tranquillitatis (after Cameron, 1992).

Titanium-rich pyroclastic deposits, such as those on the southwestern rim of Serenitatis, also may be of interest as a source of solar wind volatiles. Their regolith should be much more easily mined due to the absence of significant hard rock, may be more easily processed due to their glassy and fine-grained nature, and they may be a source of several metal and halogen by-products.

Hydrogen, water, oxygen: Hydrogen in the lunar soil, in concert with the oxygen in the various minerals, is roughly equivalent to 0.5 liter of water per cubic meter or, to a depth of about two meters, about 106 gallons per square mile.


Evaluation of the Regolith of Mare Tranquillitatis as a Source of Volatile Elements (first few pages)

Helium Resources of Mare Tranquillitatis -- Cameron (1992), pp. 16-38

Dark Mantle Material as a Source of Helium


1. Discuss the argument for and against the existence of water ice in the permanently shadowed polar regions of the moon, including comparisons with the other, relatively cold terrestrial planets, i.e., Mercury, Earth, and Mars.

2. What are the considerations that must be taken into account if one were to calculate the modern day steady state concentration of 3He in the upper one centimeter of the lunar regolith?

3. How are estimates made of titanium distribution on the Moon using remotely sensed spectral data from the Earth and from the Clementine spacecraft sensors? (Consider starting with: Clementine and Johnson, 1991))


Arnold, J.R., 1979, Ice on the Moon, Journal of Geophysical Research, v 84, 5659-5668.

Cameron, E.N., 1988, Dark Mantle Material as a Source of Helium, unpublished memorandum to G.L. Kulcinski, WCSAR-TR-AR3-8810-3.

Cameron, E.N., 1992, Helium Resouces of Mare Tranquillitatis, Technical Report, WCSAR-TR-AR3-9207-1.

Cameron, E.N., 1993, Evaluation of the Regolith of Mare Tranquillitatis as a Source of Volatile Elements , Technical Report, WCSAR-TR-AR3-9301-1

Fegley, B., Jr., and Swindle, T.D., 1993, Lurar Volatiles: Implications for Lunar Resource Utilization, in Lewis, J., Matthews, M.S., and Guerrieri, M.L., 1993, Editors,Resources of Near-Earth Space, University of Arizona Press.

Heiken, G., et al, 1991, Lunar Source Book, Cambridge University Press, Cambridge, 736p.

Johnson, J.R., et al, 1991, Journal of Geophysical Research, v 96(E3), 18861.

Lewis, J., Matthews, M.S., and Guerrieri, M.L., 1993, Editors,Resources of Near-Earth Space, University of Arizona Press.

Taylor, L.A., 1993, Evidence of Helium-3 on the Moon: Model Assumptions and Abundances, Proceedings of the Second Wisconsin Symposium on Helium-3 and Fusion Power, WCSAR-TR-AR3-9307-3, 49-56.

Watson, K., et al, 1975, The Behavior of Volatiles on the Lunar Surface, The Moon, v 13, 121.

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